@article{389, keywords = {paper}, author = {G Onida and Lucia Reining and RW Godby and Rodolfo Del Sole and W ANDREONI}, title = {Ab-initio calculations of the quasi-particule and absorption spectra of clusters: the sodium tetramer}, abstract = {We report the first ab initio quasiparticle calculation in a real cluster Na-4 within Hedin\textquoterights GW approximation for the valence electron self-energy. Our approach avoids the summations over empty states, and also eliminates the problem of residual interactions between the periodic images. Self-energy corrections open the local density approximation gap by more than 2 eV; finite-size effects on screening are shown to play an important role. The absorption spectrum calculated by including excitonic effects using our ab initio screened interaction gives a good account of the experimental photodepletion data.}, year = {1995}, journal = {Phys. Rev. Lett.}, volume = {75}, number = {5}, pages = {818-821}, month = {JUL 31}, publisher = {AMERICAN PHYSICAL SOC}, address = {ONE PHYSICS ELLIPSE, COLLEGE PK, MD 20740-3844 USA}, }